Well, to begin with, the union was already riddled with rumors. First of all, Pitt was married to Jennifer Aniston when he met Jolie filming Mr. and Mrs. Smith. Many have condemned both parties for committing adultery. Whatever the case may be, it seems as if things weren’t smooth-sailing for the now divorced duo. Since Jolie filed for divorce, both have been seeing a private judge for the settlement. She asked for full physical and joint legal custody of their kids, and rumor has it, the divorce will end up being as expensive as $400 million.